Coproduction of acetylene and hydrocyanic acid from acrylonitril

Chemistry of inorganic compounds – Nitrogen or compound thereof – Carbon containing

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585534, 585538, 585539, C01C 308, C07C 200, C07C 202

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06042799&

ABSTRACT:
In the process for preparing acetylene and hydrocyanic acid by pyrolyzing acrylonitrile in a reactor, the gaseous reaction products of the pyrolysis are quenched down to less than 100.degree. C. immediately, advantageously within seconds, preferably within .ltoreq.1 s, of leaving the pyrolysis zone.

REFERENCES:
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patent: 5804689 (1998-09-01), Schodel et al.
Lifshitz et al. Pyrolysis of Acrylonitrile at Elevated Temperature, Studies with a Single-Pulse Shock Tube. Journal of Physical Chemistry, American Chemical Society, pp. 1369-1373, 1989.
Robert H. Perry and Cecil H. Chilton. Chemical Engineers' Handbook, Fifth Edition. pp. 4-2 to 4-43, 1973.
Ullmann's Ency. Fifth Ed., vol. A1 111-112.
Int. Jrl. Chem. Kinetics, vol. 19, 61-79, 1987.
Combustion and flame 78:43-57 (1989).
American Chem. Soc., Lifshitz et al., Pyrolysis of Acrylonitrile at Elevated Temperatures . . . .

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