Copper or silver complexes with fluorinated diketones and unsatu

Details Copper or silver complexes with fluorinated diketones and unsatu Copper or silver complexes with fluorinated diketones and unsatu

1981-07-13

1984-01-10

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2604381, 260429J, 549 2, 549 3, 549 6, C07F 110, C07F 108

Patent

active

044252811

ABSTRACT:
A composition of matter of the formula ##STR1## where M is Cu(I) or Ag(I); R.sup.1 is C.sub.1 -C.sub.6 fluoroalkyl, C.sub.1 -C.sub.8 alkyl, C.sub.4 -C.sub.6 heterocycle containing O, S or N or C.sub.6 -C.sub.10 aryl; R.sup.2 is H or C.sub.1 -C.sub.6 alkyl, with the proviso that R.sup.1 and R.sup.2 together with the carbons to which they are attached may be joined together to form a C.sub.6 ring; L is an unsaturated hydrocarbon containing at least one non-aromatic unsaturation; x and y are 1 or 2; and n is from 1 to 8.

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Belford et al., Reactions of 1,4-Diazabicyclo [2.2.2] octane with Bis-(1,1,1,5,5,5,-hexafluoropentane-2,4-dionato)Cu(II), J.C.S. Dalton, 2208 (1972).
Bailey et al., Ternary Complexes of Cu(II) with Mixed Acetylacetonate and Nitrogen-containing Ligands, J.C.S. Dalton, 984 (1980).
Partenheimer and Johnson, "The Syntheses of Some New Silver Olefin Compounds of the Type (Olefin) (.beta.-diketonato)silver(I)", Inorganic Chemistry, 11, 2840-2841 (1972).

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