Copper-magnesium catalyst and method for alkylation of hydroxyar

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502344, 502345, 568794, 568804, B01J 2300, C07C 3716

Patent

active

045542660

ABSTRACT:
Hydroxyaromatic compounds such as phenol are alkylated with alkanols such as methanol in the presence of a catalyst comprising an intimate blend of magnesium oxide and copper, the latter being present in an amount up to about 2% by weight, based on said magnesium oxide. The catalyst is prepared by blending a magnesium reagent and copper in elemental or (preferably) chemically combined form and calcining the same at a temperature within the range of about 350.degree.-550.degree. C. The catalyst promotes ortho-alkylation of the hydroxyaromatic compound in high yield, minimizes decomposition of the alkanol, and has long life.

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Chem. Abstracts, 80, 120534a (1974).

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