Copper carbonyl-containing catalytic solutions

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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Details

260413, 260514M, 260532, 260533A, B01J 2712

Patent

active

040025772

ABSTRACT:
A novel catalytic composition is described, useful for treating olefins or alcohols with carbon monoxide in the preparation of carboxylic acids comprising a solution containing copper carbonyl and a hydrated boron fluoride which optionally may contain a mineral acid such as sulfuric acid, phosphoric acid or hydrogen fluoride. The copper carbonyl functions as a co-catalyst for the hydrated boron trifluoride to enhance selectivity. The catalysts are especially suited for the preparation of neo acids.

REFERENCES:
patent: 1914785 (1933-06-01), Oxley
patent: 2324073 (1943-07-01), Gaylor et al.
patent: 3099687 (1963-07-01), Rohlffs et al.
patent: 3262954 (1966-07-01), Wehe et al.

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