Copper base alloys and terminals using the same

Details Copper base alloys and terminals using the same Copper base alloys and terminals using the same

1999-08-24

2001-07-03

Ip, Sikyin (Department: 1742)

Metal treatment

Stock

Copper base

C148S435000, C148S554000, C338S220000

Reexamination Certificate

active

06254702

ABSTRACT:

BACKGROUND OF THE INVENTION
This invention relates to copper base alloys for use in connector terminals in automobiles and other applications, as well as connector terminals that are made of those copper base alloys.
In response to the recent advances in electronics technology, connector terminals for use in automobiles and other applications have increasingly been required to satisfy the need for higher packing density, smaller scale, lighter weight and higher reliability. On the other hand the constant improvement in the engine performance has led to a higher temperature in the engine room. Under these circumstance, there has risen the need that the copper base alloys for terminals that are used as conductive materials on the engine should have even higher reliability and heat resistance. However, brass that has heretofore been used as an inexpensive copper base alloy for terminals has low electrical conductivity (to take C26000 as an example, its electrical conductivity is 27% IACS); it also has problems with anti-stress relaxation characteristics, corrosion resistance and stress corrosion cracking resistance. Further, phospher bronze has high strength but its electrical conductivity (hereunder simply referred to as “conductivity”) is also low (to take C52100 as an example, its conductivity is ca. 12% IACS); in addition, it has problems with anti-stress relaxation characteristics, and from an economic viewpoint (high price). Cu—Sn—Fe—P alloys have been developed with a view to solving those problems of brass and phospher bronze. For example, Cu—2.0Sn—0.1Fe—0.03P has a conductivity of 35% IACS and is superior in strength; however, its anti-stress relaxation characteristics has not been completely satisfactory in view of its use as an alloy for terminals.
For manufacturing highly reliable automotive terminals, it is necessary to use copper base alloys that are superior in strength, spring limits and conductivity and that will cause neither stress relaxation nor corrosion after prolonged use. However, none of the conventional copper base alloys, i.e., brass, phosphor bronze and Cu—Sn—Fe—P alloys, have satisfied those requirements.
A further problem is that the terminals manufactured from the aforementioned copper base alloys reflect the characteristics of those alloys in a straightforward manner. The terminals using brass, phosphor bronze or Cu—Sn—Fe—P alloys do not satisfy the requirements for high conductivity and good anti-stress relaxation characteristics simultaneously, so they will generate heat by themselves, potentially causing various problems including oxidation, plate separation, stress relaxation, circuit voltage drop, and the softening or deformation of the housing.
SUMMARY OF THE INVENTION
An object, therefore, of the present invention is to provide a copper base alloy for terminals that is superior in all aspects of tensile strength, spring limits, conductivity, anti-stress relaxation characteristics and bending workability. Another object of the present invention is to provide a terminal which at least has a spring made of the above stated alloy or a terminal the whole of which, inclusive of its spring, is made of the above stated alloy formed in one piece, either terminal being superior in resistance at low voltage and low current and in anti-stress relaxation characteristics.
In order to attain these objects, the present inventors conducted repeated test and research efforts on Cu—Ni—Sn—P alloys, as well as Cu—Ni—Sn—P—Zn alloys and found that characteristics satisfactory in terms of tensile strength, conductivity, anti-stress relaxation characteristics, anti-migration characteristics, as well as bending workability could be attained by selecting appropriate compositions for those alloys, and causing uniform precipitation of a fine precipitate of a Ni—P compound. It was also found that terminals with a built-in spring that was produced from those copper base alloys or terminals that were entirely made of those copper base alloys including a spring as an integral part possessed superior characteristics.


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