Copolymers of alpha-n-alkylstyrenes and styrene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252 9, 252 12, 260 336UA, 526218, 5262321, 526347, C08F21208

Patent

active

041951441

ABSTRACT:
There is described novel copolymers of styrene and alpha-n-alkylstyrenes taining at least eleven carbon atoms in the alkyl group. The copolymers, which contain at least 20 mole percent of the alpha-n-alkylstyrenes, are solids and have greater durability with lower coefficients of friction than comparable styrene homopolymers. The copolymers are produced by anionic initiated copolymerization using metallic sodium as the catalyst or by radical initiated copolymerization using benzoyl peroxide or azobisisobutyronitrile as the catalyst.

REFERENCES:
patent: 2448976 (1948-09-01), Heligmann
patent: 3139416 (1964-06-01), Lumb et al.
patent: 3169948 (1965-02-01), Hardy
patent: 4016348 (1977-04-01), Adams

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