Coordination catalyst systems employing chromium...

Details Coordination catalyst systems employing chromium... Coordination catalyst systems employing chromium...

2005-09-20

2005-09-20

Choi, Ling-Siu (Department: 1713)

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

C502S103000, C502S117000, C502S167000, C502S120000, C502S080000, C526S161000, C526S172000

Reexamination Certificate

active

06946420

ABSTRACT:
The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound in controlled amounts, and methods for preparing the same. The resulting catalyst system exhibits enhanced activity for polymerizing olefins and yields polymer products having very good morphology.

REFERENCES:
patent: 2825721 (1958-03-01), Hogan et al.
patent: 4131452 (1978-12-01), Collin
patent: 4176090 (1979-11-01), Vaughan et al.
patent: 4216188 (1980-08-01), Shabria et al.
patent: 4238364 (1980-12-01), Shabtai
patent: 4248739 (1981-02-01), Vaughan et al.
patent: 4271043 (1981-06-01), Vaughan et al.
patent: 4367163 (1983-01-01), Pinnavaia et al.
patent: 4375406 (1983-03-01), Santilli
patent: 4629712 (1986-12-01), Pinnavaia et al.
patent: 4637992 (1987-01-01), Lewis et al.
patent: 4761391 (1988-08-01), Occelli
patent: 4859648 (1989-08-01), Landis et al.
patent: 4981825 (1991-01-01), Pinnavaia et al.
patent: 4995964 (1991-02-01), Gortsema et al.
patent: 5064802 (1991-11-01), Stevens et al.
patent: 5225500 (1993-07-01), Elder et al.
patent: 5238892 (1993-08-01), Chang
patent: 5241025 (1993-08-01), Hlatky et al.
patent: 5243002 (1993-09-01), Razavi
patent: 5250277 (1993-10-01), Kresge et al.
patent: 5308811 (1994-05-01), Suga et al.
patent: 5321106 (1994-06-01), LaPointe
patent: 5360775 (1994-11-01), Suda et al.
patent: 5362825 (1994-11-01), Hawley et al.
patent: 5395808 (1995-03-01), Miller et al.
patent: 5399636 (1995-03-01), Alt et al.
patent: 5403799 (1995-04-01), Miller et al.
patent: 5403809 (1995-04-01), Miller et al.
patent: 5427991 (1995-06-01), Turner
patent: 5541272 (1996-07-01), Schmid et al.
patent: 5569634 (1996-10-01), Miller et al.
patent: 5624878 (1997-04-01), Devore et al.
patent: 5633419 (1997-05-01), Spencer et al.
patent: 5643847 (1997-07-01), Walzer, Jr.
patent: 5714424 (1998-02-01), Warthen et al.
patent: 5753577 (1998-05-01), Hamura et al.
patent: 5807800 (1998-09-01), Shamshoum et al.
patent: 5807938 (1998-09-01), Kaneko et al.
patent: 5817724 (1998-10-01), Aoki et al.
patent: 5830820 (1998-11-01), Yano et al.
patent: 5866663 (1999-02-01), Brookhart et al.
patent: 5880241 (1999-03-01), Brookhart et al.
patent: 5880323 (1999-03-01), Brookhart, III et al.
patent: 5886224 (1999-03-01), Brookhart et al.
patent: 5891963 (1999-04-01), Brookhart et al.
patent: 5928982 (1999-07-01), Suga et al.
patent: 5955555 (1999-09-01), Bennett
patent: 5973084 (1999-10-01), Suga et al.
patent: 6110858 (2000-08-01), Kaneko et al.
patent: 6184171 (2001-02-01), Shih
patent: 6214761 (2001-04-01), Bennett
patent: 6399535 (2002-06-01), Shih et al.
patent: 19943936 (1999-09-01), None
patent: 426637 (1991-05-01), None
patent: 426638 (1991-05-01), None
patent: 490226 (1992-06-01), None
patent: 0 546503 (1993-06-01), None
patent: 546503 (1996-05-01), None
patent: 849288 (1997-12-01), None
patent: 849292 (1998-06-01), None
patent: 874006 (1998-10-01), None
patent: 881232 (1998-12-01), None
patent: 2-78663 (1990-03-01), None
patent: 10-338516 (1998-12-01), None
patent: 11-292912 (2000-03-01), None
patent: WO 91/14713 (1991-10-01), None
patent: WO 92/00333 (1992-01-01), None
patent: WO 96/23010 (1996-08-01), None
patent: WO 97/19959 (1996-10-01), None
patent: WO 97/48743 (1997-12-01), None
patent: WO 98/27124 (1998-06-01), None
patent: WO 98/30612 (1998-07-01), None
patent: WO 99/46302 (1999-09-01), None
patent: WO 99/46303 (1999-09-01), None
patent: WO 99/46304 (1999-09-01), None
patent: WO 00/50475 (2000-08-01), None
patent: WO 01/25149 (2001-04-01), None
patent: WO 01/32721 (2001-05-01), None
patent: WO 01/42320 (2001-06-01), None
patent: WO 01/49747 (2001-07-01), None
U.S. Appl. No. 09/431,803, filed Nov. 1, 199, Shih.
U.S. Appl. No. 10/120,289, filed Apr. 10, 2002, Shih et al.
U.S. Appl. No. 10/120,291, filed Apr. 10, 2002, Shih.
U.S. Appl. No. 10/120,310, filed Apr. 10, 2002, Shih et al.
U.S. Appl. No. 10/120,317, filed Apr. 10, 2002, Shih.
U.S. Appl. No. 10/120,331, filed Apr. 10, 2002, Shih.
U.S. Appl. No. 60/287,601, Shih et al., filed Apr. 30, 2001.
U.S. Appl. No. 60/287,602, Shih et al., filed Apr. 30, 2001.
U.S. Appl. No. 60/287,607, Shih et al., filed Apr. 30, 2001.
U.S. Appl. No. 60/287,617, Shih et al., filed Apr. 30, 2001.
George J.P. Britovsek, Vernon C. Gibson, and Duncan F. Wass, Agnew. Chem. Int. Ed 1999, vol. 38, pp 428-447 “The Search for New-Generation Olefin Polymerization Catalysts: Life Beyond Metallocenes”.
Pasquale Longo, Fabia Grisi, Antonio Proto, Adolfo Zambelli, “New Ni(II) based catalysts in the polymerization of olefins”, Macromol. Rapid Commun. 19, 31-34 (1998).
Lynda K. Johnson, Stefan Mecking, and Maurice Brookhart, “Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium (II) Catalysts”, 1996 American Chemical Society, vol. 118, No. 1, 1996.
Lynda K. Johnson, Christopher M. Killian, and Maurice Brookhart, “New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and a-olefins”, Journal American Chemical Society 1995, 177, 6414-6415.
“Novel polymerization reactions catalyzed by homogeneous Pd(II) and Ni(II) a-dimino complexes”, CatTech Highlights, Mar. 1997; p. 65-66.
“Move Over Metallocenes”, Chemical Week, Apr. 29, 1998, p. 72.
“New Catalysts to Polymerize Olefins”, C&EN, Apr. 13, 1998, pp 11-12.
Rip A. Lee, Rene J. Lachicotte, and Guillermo C. Bazan, “Zirconium Complexes of 9-Phenyl-9-borataanthracene. Synthesis, Structural Characterization, and Reactivity”, Journal American Chemical Society 1998, 120, 6037-6046.
Brooke L. Small, Maurice Brookhart, and Alison M.A. Bennett, “Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene”, Journal American Chemical Society 1998, 120, 4049-4050.
John A. Ewen, Robert L. Jones, A. Razavi, “Syndiospecific Propylene Polymerizations with Group 4 Metallocenes”, J. Am. Chem. Soc. 1988, 110, 6255-6256.
Thomas J. Pinnavaia “Intercalated Clay Catalysts”, Science, Apr. 22, 1983, vol. 220, No. 4595, pp 365-371.
Yoshinori Suga, Eiji Isobe, Toru Suzuki, Kiyotoshi Fujioka, “Novel Clay Mineral-Supported Metallocene Catalysts For Olefin Polymerization,” Publication Presentation at MetCon 99: “Polymers in Transition,” Jun. 9-10, 1999, Houston, Texas, United States of America.
Nakamura, Yuji et al., “Clay Column Chromatography for Optical Resolution: Partial Resolution of 1,1′-Binaphthol on Optically Active [Co(phen)3-x(am)x]n+−Montmorillonite Columns”; Clay Sci. (1990), 8(1), 17-23, XP000983072, p. 18.

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