Conversion of tertiary alcohols to C8+ olefins

Details Conversion of tertiary alcohols to C8+ olefins Conversion of tertiary alcohols to C8+ olefins

1991-11-12

1992-10-20

McFarlane, Anthony

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

From nonhydrocarbon feed

585639, 585324, C07C 124, C07C 1102

Patent

active

051571927

ABSTRACT:
A process for the conversion of tertiary alcohols to C.sub.8 + olefin products over a zeolite catalyst, such as zeolite Beta. The process is particularly useful for the conversion of t-butyl alcohol to 2,2,4-trimethyl pentene. A two-step partial oxidation/dimerization process to yield C.sub.8 + olefin products is also disclosed.

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Abstract 88-52503 Japanese Patent 63101337A.
Kofke, T., et al, "A Temperature-Programmed Desorption Study of Olefin Oligomerization in H--ZSM-5", Journal of Catalysis 115, pp. 233-243 (1989).
Chang, C. D. et al., "The Conversion of Methanol and Other O-Compounds to Hydrocarbons over Zeolite Catalysts", Journal of Catalysis 47, pp. 249-259 (1977).

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