Conversion of oxides of nitrogen to nitrogen for pollution abate

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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423351, C01B 2100

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active

046631356

ABSTRACT:
A process for removing oxides of nitrogen from a gas in which the molar ratio of NO to NO.sub.2 is greater than 1. Sufficient NO is oxidized by the reaction NO+2HNO.sub.3 =H.sub.2 O+3NO.sub.2 by a solution whose HNO.sub.3 concentration is maintained above about 20% to form a gas whose molar ratio of NO to NO.sub.2 is close to 1. Substantially equivalent amounts of NO and NO.sub.2 are absorbed by a solution whose pH is maintained below about 2 containing HNO.sub.3 and dissolved NH.sub.3. The absorbed oxides of nitrogen react with the dissolved NH.sub.3 at a temperature above about 50.degree. C. to form elemental nitrogen and water. The process can be carried out in several steps or in substantially one step.

REFERENCES:
patent: 3453071 (1969-07-01), Schmitt et al.
patent: 4397719 (1983-08-01), Yoshida
patent: 4419333 (1983-12-01), Rues et al.
patent: 4427503 (1984-01-01), Heilgeist

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