Conversion of organic sulfides to corresponding sulfoxides

Details Conversion of organic sulfides to corresponding sulfoxides Conversion of organic sulfides to corresponding sulfoxides

1977-06-29

1978-09-12

Gotts, Lewis

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260607AL, C07C14714

Patent

active

041137841

ABSTRACT:
Suitable organic sulfides are converted to the corresponding organic sulfoxides by contacting with at least one suitable hydrocarbyl sulfoxide, a protonic acid, and a suitable metal promoter. Alternatively, if hydrogen chloride is the protonic acid, graphite or suitable metal promoters can be employed.

REFERENCES:
patent: 2787595 (1957-04-01), Webb
patent: 2859248 (1958-11-01), Louthan
patent: 2935533 (1960-05-01), Hubenett
patent: 3708542 (1973-01-01), Douchet et al.
patent: 3808112 (1974-04-01), Thibault et al.
J. Org. Chem., 40(21), 3152-4, (1975).
J. Org. Chem., 28, 3246-7, (1963).
J. Org. Chem., 23(7), 2028-9, (1958).

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