Conversion of mono-valent thallium to tri-valent thallium

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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423395, 423495, 423544, C07F 500

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041137566

ABSTRACT:
A mono-valent thallium compound is converted to a trivalent thallium compound by treating the thallium (I) compound with molecular oxygen in the presence of a Group VIII noble metal catalyst and in the presence of a promoter comprising an alkali metal compound to oxidize the thallium (I) compound to a thallium (III) compound.

REFERENCES:
patent: 3399956 (1968-09-01), Hirose et al.
patent: 3436409 (1969-04-01), Hill et al.
patent: 3479262 (1969-11-01), MacLean et al.
patent: 3594395 (1971-07-01), Taylor et al.
Spencer, L., Anorg. Chem. vol. 44 pp. 379-407 (1905).
Spiro et al., J. Chem. Soc. pp. 78-96 (1965).
Chemical Abstracts, 64 13800h (1966).
Chemical Abstracts, 67 96372e (1967).
Chemical Abstracts, 63 1471a (1965).
Chemical Abstracts, 73 47165e (1970).

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