Conversion of methane into larger organic hydrocarbons

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585359, 585469, 585642, 585733, C07C 1120, C07C 1132, C07C 100

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047958430

ABSTRACT:
Organic hydrocarbons which comprise useful compounds may be obtained in a two-step process utilizing methane as a feedstock. The desired compounds are prepared by treating said methane with a halogenating agent such as chlorine, followed by contacting the methyl halide with a conversion catalyst comprising a silicalite. The silicalite which is employed is a silica polymorph consisting of crystalline silica which, after calcination in air at a temperature of 600.degree. C. for 1 hour, has a mean refractory index of 1.39.+-.0.01 and a specific gravity at 25.degree. C. of 1.70.+-.0.05 g/cc.

REFERENCES:
patent: 2488083 (1949-11-01), Gorin et al.
patent: 3894105 (1975-07-01), Chang et al.
patent: 4384159 (1983-05-01), Diesen
patent: 4524234 (1985-06-01), Kaiser
patent: 4579996 (1986-04-01), Fontfreide et al.

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