Conversion of methane

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis

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Details

585658, 585943, C07C 200, C07C 5327

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active

050157981

ABSTRACT:
There is provided a process for the direct partial oxidation of methane with oxygen, whereby organic compounds comprising higher hydrocarbons including C.sub.5 + liquid hydrocarbons are produced. The catalyst used in this reaction may be a ZSM-5 catalyst. The process involves the use of an initial cofeed, such as propane, in admixture with the methane and oxygen to induce the formation of liquid hydrocarbons. As the reaction progresses, the flow of cofeed is shut off, and liquid hydrocarbons continue to be produced.

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patent: 4618732 (1986-10-01), Gesser et al.
patent: 4695663 (1987-09-01), Hall et al.
"Preparation of Aromatic Hydrocarbons From Methane In The Presence of O.sub.2 ", by S. S. Shepelev and K. G. Ione, Mar. 22, 1983, pp. 323-325.
"Syntheses of Hydrocarbons From C.sub.1 Compounds, Using Zeolite Catalysts", by S. S. Shepelev and K. G. Ione, 1984, pp. 284-288.
"Oxidation of Methane Over H-ZSM-5 and Other Catalysts", by J. R. Anderson & P. Tsai, 1985, pp. 141-152.
"The Effect of Oxygen on the Conversion of Light Paraffins on ZSM-5 Zeolites", by Gabriele Centi and Giorgio Golinelli, 1989, pp. 452-462.
"Oxidative Synthesis of Higher Hydrocarbons from Methane on Zeolites", by S. S. Shepelev and K. G. Ione, 1989, pp. 362-370.

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