Conversion of indene to (1S)-amino-(2R)-indanol free of any ster

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing oxygen-containing organic compound

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4352522, 585812, 210660, C12P 702, C12N 120, B01D 1500, C07C 700

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active

058719814

ABSTRACT:
A method for preparing (1S)-amino-(2R)-indandiol substantially free of its stereoisomers is presented. The method comprises culturing indene with Rhodococcus sp. ATCC 55805, recovering the indandiol and subjecting the indandiol to chiral specific crystallization, treatment with strong acid and reverse ion pair extraction.

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Gibson et al, "Desaturation, dioxygenation, and monooxygenation reactions catalyzed by naphthalene dioxygenase from Pseudomonas sp. strain 9816-4", Chemical Abstrats, vol. 123, Abs. No. 50834 (1995).
Bezborodov et al., "News Strain of Rhodococcus erythropolis bacteria", 1993, WPI No. 93-318308 (Title Only of SU 1752767).
Wackett et al., "Benzylic Monooxygenation Catalyzed by Toluene Dioxygenase from Pseudomonas putida", Biochemistry, vol. 27, pp. 1360-1366 (1988).
Gibson et al. "Desaturation, dioxygenation and monooxygenation reactions catalyzed by naphthalene dioxygenase from Pseudomonas sp. strain 9186-4," J. Bacteriol. (May 1995) 177(10):2615-21, May 1995.

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