Conversion of cyclohexanol to .epsilon.-caprolactone

Details Conversion of cyclohexanol to .epsilon.-caprolactone Conversion of cyclohexanol to .epsilon.-caprolactone

1978-04-18

1980-01-15

Rotman, Alan L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

568567, C07D31304, C07C17908

Patent

active

041838637

ABSTRACT:
Cyclohexanol is first autoxidized to a peroxide intermediate and then contacted with selenium dioxide catalyst and a base to afford .epsilon.-caprolactone.

REFERENCES:
patent: 2362439 (1944-11-01), Ruzicka et al.
patent: 2462337 (1946-08-01), Shechter
patent: 3428656 (1969-02-01), Weiss et al.
patent: 3577216 (1971-04-01), Weiss et al.
patent: 3590080 (1971-06-01), Beesley et al.
Kortum et al., Pure and Applied Chemistry, vol. 1, Nos. 2-3, 1961, Dissociation Constants of Organic Acids in Aqueous Solution.

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