Conversion of carbon dioxide to methanol and/or dimethyl...

Chemistry: fischer-tropsch processes; or purification or recover – With preliminary reaction to form hydrogen or a carbon oxide – Water utilized in the preliminary reaction

Reexamination Certificate

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Reexamination Certificate

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07906559

ABSTRACT:
The invention discloses a method of converting carbon dioxide to methanol and/or dimethyl ether using any methane source or natural gas consisting of a combination of steam and dry reforming, in a specific ratio to produce a 2:1 molar ratio of hydrogen and carbon monoxide with subsequent conversion of the CO and H2mixture exclusively to methanol and/or dimethyl ether. This method is termed the BI-REFORMING™ process. Dehydrating formed methanol allows producing dimethyl ether (DME) using any suitable catalytic method, including use of solid acid catalysts. When recycling formed water into the bi-reforming step the conversion of carbon dioxide with methane produces exclusively dimethyl ether without any by-product formation and complete utilization of hydrogen.

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patent: 5599638 (1997-02-01), Surampudi et al.
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patent: WO 2006/113294 (2006-10-01), None
patent: WO 2007/014487 (2007-02-01), None
International Search Reports for PCT/US2008/067462, Sep. 2008.
International Search Report and the Written Opinion of the International Searching Authority, application No. PCT/US2008/067480, dated Oct. 1, 2008.

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