Conversion of aromatics to iso-paraffins using a NaAlCl.sub.4 /H

Chemistry of hydrocarbon compounds – Saturated compound synthesis

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585940, 585741, 585752, C07C 527

Patent

active

045131635

ABSTRACT:
The present invention provides a process for producing iso-paraffins from aromatic hydrocarbons comprising contacting the aromatic hydrocarbon or aromatic hydrocarbon-containing feed with a molten salt system comprising sodium tetrachloroaluminate (NaAlCl.sub.4) and up to about 25 weight percent hydrogen tetrachloroaluminate (HAlCl.sub.4) at a temperature above about 155.degree. C., i.e. that required to maintain the molten state of said mixture, whereby the ring structure is opened and the aromatic compound is rearranged to an iso-paraffin of the same or substantially the same molecular weight.

REFERENCES:
patent: 1825294 (1931-09-01), Wolcott
patent: 2394898 (1946-02-01), Cheney et al.
patent: 2408941 (1946-10-01), Mavity et al.
patent: 2464201 (1949-03-01), Latchum
patent: 2475358 (1949-07-01), Moore et al.

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