Conversion of allyl ethers to acetals

Details Conversion of allyl ethers to acetals Conversion of allyl ethers to acetals

1985-07-02

1987-04-14

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568605, 568594, 560186, 2604106, 2604109R, C07C 43303

Patent

active

046580697

ABSTRACT:
9-methoxy-7-nonenal may be isomerized in the presence of methanol and ruthenium chloride to provide 1,1,9,9-tetramethoxynonane. The rates of reaction are increased by pre-formation of 1,1,9-trimethoxy-7-nonene and removal of the water generated prior to conducting the isomerization reaction.

REFERENCES:
patent: 3584010 (1971-06-01), Morbet
Moisiev et al., Acad. Sci. USSR, Dokl. Chem. Section, 1960, pp. 801-804.
Moisiev et al., Soviet Inventions Illustrated, Mar. 1965.
Stern et al., Proceedings Chem. Soc., Oct. 1961, p. 370.

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