Conversion of alkanes to unsaturated carboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 5116

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057056854

ABSTRACT:
Alkanes are converted to unsaturated carboxylic acids by contacting an alkane with an oxidizing agent and a heteropolyacid or polyoxoanion comprising (1) at least 9 atoms of a first framework metal or metals comprising molybdenum, tungsten or vanadium or combinations thereof and (2) 1 to 3 atoms of a second framework metal or metals comprising zinc or a transition metal different from the first framework metal.

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Pope et al., Heteropoly and Isopoly Oxometalates, 31-32 Springer Verlag, New York (1983).
Blake et al., J.Chem.Soc. Dalton Trans., p.2509 (1985).
Uemura et al., J.Chem.Soc. Dalton Trans., p.2565 (1973).

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