Conversion of alkane and/or cycloalkane thiols to disulfide with

Details Conversion of alkane and/or cycloalkane thiols to disulfide with Conversion of alkane and/or cycloalkane thiols to disulfide with

1979-08-17

1981-07-07

Daus, Donald G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfur containing

C07C14910

Patent

active

042776236

ABSTRACT:
An alkane and/or cycloalkane thiol is converted to disulfide with oxygen or air in presence of a catalyst system comprising a cobalt molybdate-alkali metal- and/or an alkaline earth metal hydroxide. A solvent, e.g., an alcohol or an alcohol-water mixture is employed. In one embodiment, 2-methyl-2-propane thiol (tertiary-butyl mercaptan) is converted.

REFERENCES:
patent: 2574884 (1951-11-01), Mertz et al.
patent: 2966453 (1960-12-01), Gleim et al.
patent: 3340324 (1967-09-01), Warner
patent: 3565959 (1971-02-01), Takase et al.
patent: 3978137 (1976-08-01), Frame
patent: 4090954 (1978-05-01), Ward

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