Controlled radical polymerization process using a small...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S220000, C526S317100, C526S318000, C525S094000, C525S027000, C525S263000

Reexamination Certificate

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06911511

ABSTRACT:
The invention relates to a process for the polymerization of at least one monomer which can be polymerized via a radical route, in the presence of a stable free radical and of a polymerization initiator, such that, per 100 mol of monomer, the molar amounts of stable radical (SFR) and of initiator (INIT) are such that [(SFR)×FSFR]/[(INIT)×FINIT]<0.15 and FSFR×(SFR)<0.2 mol, in which FSFRrepresents the functionality of the stable free radical and FINITrepresents the functionality of the initiator. The process according to the invention has advantageous kinetics, allows the production of grafted or block copolymers and can be carried out in an extruder.

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A. Forrester et al., “Organic Chemistry Of Stable Free Radicals”, Table of Contents, Academic Press, 1968.

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