Controlled free radical grafting from polyolefins

Details Controlled free radical grafting from polyolefins Controlled free radical grafting from polyolefins

2007-01-18

2010-11-02

Rabago, Roberto (Department: 1796)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

C526S113000, C526S118000, C526S119000, C526S161000, C526S169100, C526S171000, C526S172000, C526S281000, C526S329000, C525S245000, C525S248000

Reexamination Certificate

active

07825200

ABSTRACT:
Described are novel monomers bearing functionalities capable of initiating control free radical reactions, and a novel process using these initiating monomers in the co-polymerization of an olefin for the formation of well-controlled polyethylene graft polymers where the graft component is derived from controlled free radical polymerization reactions. The initiating monomers are produced by combining an amount of 5-norbornen-2-ol with a hydride or amine for a predetermined amount of time to form a mixture; and adding an amount of an alkyl or acyl halide to said mixture. Polymerization of an olefin with an initiating monomer is conducted in the presence of a metal compound, where the metal compound is comprised of a Group VIII transition metal complex.

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