Controlled catalystic and thermal sequential pyrolysis and hydro

Details Controlled catalystic and thermal sequential pyrolysis and hydro Controlled catalystic and thermal sequential pyrolysis and hydro

1992-10-27

1994-06-14

Pal, Asok

Chemistry of hydrocarbon compounds

Production of hydrocarbon mixture from refuse or vegetation

From synthetic resin or rubber

585242, C07C 100, C07C 400

Patent

active

053211740

ABSTRACT:
A process of using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents.

REFERENCES:
patent: 5216149 (1993-06-01), Evans et al.

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