Control of pests with annonaceous acetogenins

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

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549320, 549323, A01N 4308, C07D30712

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active

048553190

ABSTRACT:
Tetrahydrofuranoid acetogenins characteristic of the Annonaceae plant family have been found to have potent pesticidal and feeding deterrent activity against a diverse variety of pests such as mosquito larvae, spider mites, aphids, the Mexican bean beetle, striped cucumber beetle, blowfly larvae, and nematodes. A new acetogenin called "asimicin" having the following structural formula has been isolated and is typical of the subject class of useful compounds: ##STR1##

REFERENCES:
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Jolad et al. I, "Desacetyluvaricin Fram, etc", J. Nat. Prod., 48, 644 (1985).
Jolad et al. II, "Uvaricin, A New Antitumor, etc", JOC, 47, 3151 (1982).
Dabrah et al. I, "Rollinicin and, etc", Phytochemistry, 23, 2013 (1984).
Dabrah et al. II, "Rollinone, A New Cytotoxic, etc", J. Nat. Prod., 47, 652 (1984).
Thomas R. Hoye et al., "On the Stereochemistry of the Bistetrahydrofuranyl Moiety of Uvaricin: Proton Chemical Shifts Can Play a Crucial Role in Complex Structure Determination", J. Am. Schem. Soc., 109: 4402-4403 (1987).
George R. Pettit et al., "Isolation and Structure of Rolliniastatin 1 from the South American Tree Rollinia mucosa", Can. J. Chem., 65: 1433-1435 (1987).

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