Control of a solution process for polymerization of ethylene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in tubular or loop reactor

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526 65, 526116, 5261247, 5261249, 5261252, 5261257, 526142, 526153, 502110, 502115, C08F 4654

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active

055895557

ABSTRACT:
A solution process for the preparation of high molecular weight polymers of alpha-olefins selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and C.sub.3 -C.sub.12 higher alpha-olefins is disclosed. Ethylene and/or mixtures of ethylene and C.sub.3 -C.sub.12 higher alpha-olefins are polymerized under non-isothermal conditions in a tubular reactor or in a system of reactors which operate under different conditions, in the presence of a catalytic amount of a titanium-containing coordination catalyst in an inert solvent at a temperature in excess of 105.degree. C. The improvement is characterized in that:

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