Continuous production of 1,1,1,3,3,3-hexafluoropropane and 1-chl

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 1700

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058116044

ABSTRACT:
A process for the continuous production of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and/or 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa) in the liquid phase wherein the HFC-235fa and/or HFC-236fa serve as solvents for the reaction. When the reaction is conducted in the presence of a catalyst of SbF.sub.3, SbF.sub.5 or a mixture of SbF.sub.5 and HSO.sub.3 F, the reaction mass is unexpectedly less corrosive to the reaction vessel used.

REFERENCES:
patent: 5395997 (1995-03-01), Van Der Puy et al.
patent: 5608126 (1997-03-01), Morikawa et al.
patent: 5608127 (1997-03-01), Gumprecht

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