Continuous process for the preparation of poly(vinyl acetate) fo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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159 471, 523343, C08F 800

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060545305

ABSTRACT:
An improved process for the continuous production of poly(vinyl alcohol) which involves purifying poly(vinyl acetate) paste exiting from a polymerization reactor and dissolving the substantially pure poly(vinyl acetate) in a hydrolytic alcohol-containing solvent for subsequent saponification to produce poly(vinyl alcohol). Poly(vinyl acetate) paste, containing poly(vinyl acetate), vinyl acetate, and solvent, is heated to a temperature above the glass transition temperature but below a temperature which will degrade the poly(vinyl acetate) and is fed into a flashing area of an extruding devolatilization device. Vinyl acetate and solvent are flashed through vent ports in the flashing area of the devolatilization device and can then be recycled to a polymerization reactor, if desired. A substantially pure poly(vinyl acetate) melt, exiting the flashing area, is conveyed to a mixing area of the devolatilization device where it is mixed with a hydrolytic alcohol-containing solvent to form a solution for subsequent processing in a saponification unit.

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Devolatilization of Polymers, edited by J. A. Biesenberger (Hanser, 1983), pp. 65-85.
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Polymer Handbook, 3.sup.rd ed., edited by J. Brandrup and E. H. Innergut. Wiley, 1989, p. V/71

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