Continuous process for the preparation of acetic anhydride or mi

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid anhydrides

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562893, 562898, C07C 5156, C07C 5112, C07C 51573

Patent

active

052929485

ABSTRACT:
Disclosed is a continuous process for the preparation of acetic anhydride which comprises carbonylating a mixture comprising (i) methyl iodide and (ii) methyl acetate and/or dimethyl ether in the presence of a rhodium catalyst and a promoter wherein the concentration of mesityl oxide in the carbonylation mixture is suppressed by the presence therein of at least 100 ppm of dissolved ferrous and/or cobaltous ion.

REFERENCES:
patent: 4046807 (1977-09-01), Kuckertz
patent: 4115444 (1978-09-01), Rizkalla
patent: 4132734 (1979-01-01), Singleton
patent: 4252748 (1981-02-01), Hoch et al.
patent: 4358411 (1982-11-01), Porcelli et al.
patent: 4534912 (1985-08-01), Cook

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