Continuous process for the manufacture of ethylene glycol

Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction

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C07C 2706

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active

044342470

ABSTRACT:
This invention relates to the manufacture of valuable alcohols containing 1 to 2 carbon atoms, especially glycol and ethanol from the reaction of hydrogen and carbon monoxide, by a homogeneous catalytic process using as a catalyst a solubilized ruthenium carbonyl complex. The invention also encompasses the catalyst formed during the process. A particular desirable embodiment of the invention is the continuous operation thereof in a manner which minimizes inhibition of glycol formation and represses formation of adverse or undesirable glycol byproducts.

REFERENCES:
patent: 2534018 (1950-12-01), Gresham et al.
patent: 2535060 (1950-12-01), Gresham
patent: 2549470 (1951-04-01), Howk et al.
patent: 2636046 (1953-04-01), Gresham
patent: 3110747 (1963-11-01), Mullineaux
patent: 3285948 (1966-11-01), Butter
patent: 3539634 (1970-11-01), Olivier et al.
patent: 3579566 (1971-05-01), Fenton
patent: 3833634 (1974-09-01), Pruett et al.
patent: 3957857 (1976-05-01), Pruett et al.
patent: 4133966 (1979-01-01), Pretzer et al.
patent: 4162261 (1979-07-01), Kaplan
patent: 4170605 (1979-10-01), Williamson et al.
Pruett, Roy L., Annls. New York Academy of Sciences, vol. 295, pp. 239-248 (1977).
Fonseca, R. et al. High Pressure Science and Technology, 6th AIRAPT Conference (Chapt. "High Pressure Synthesis of Polyalcohols by Catalytic Hydrogenation of Carbon Monoxide") pp. 733-738, Plenum Press, N.Y. (1979).
Deluzarche, A. et al. Erdol and Kohle-Erdgas-Petrochemie vereinigt mit Brennstoff-Chemie, Bdg. 32, Heft 7, pp. 313-316 (Jul. 1979).
Catalytica Letters, vol. 5 No. 1 (1/79) reporting on J. S. Bradley Paper No. 54 of the 1st. Int. Symp. on Homogeneous Catalysis held at Corpus Christi, Tex. on 11/29 through 12/1/78.
J. W. Rathke and H. M. Feder, J. Amer. Chem. Soc., 100 (11) pp. 3623-3625 (May 24, 1978).
Japanese Patent Application (Kokai) No. 52-73804/77 (Derwent Abstract and Translation).
Lyons, J. C. S. Chem. Comm. pp. 412, 413 (1975).
Wender et al., Chem. and Ind. pp. 1694-1695 (1958).
Bianchi et al., Journal of Organometallic Chemistry, vol. 141, pp. 107-111 (1977).
Bianchi et al., La Chimica & L'Industrie, vol. 60, pp. 588-592 (1978), including a translation thereof.

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