Continuous process for the isomerization of olefins with regener

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By skeletal isomerization

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502 38, 502 41, 502 55, C07C 522, C07C 527

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active

056866488

ABSTRACT:
Continuous process for the skeletal isomerization of n-olefins containing at the most 20 carbon atoms, in the presence of a catalyst essentially constituted by alumina and titanium, in which a charge containing the said n-olefins is made to flow through at least one fluidized bed reaction zone, the catalyst flowing into each reaction zone. The catalyst drawn off from the final reaction zone is passed into a regeneration zone, at the outlet of which it is passed into a zone where it undergoes a steam treatment prior to its reintroduction into the first reaction zone. The process is performed in the presence of steam, so that the catalyst is in contact with 3 to 85 wt. % (based on the catalyst weight) of steam. The water/olefin charge molar ratio in the reaction zone is between 0.1 and 3.

REFERENCES:
patent: 3558733 (1971-01-01), Myers
patent: 4225419 (1980-09-01), Myers
patent: 4367362 (1983-01-01), Franz et al.
patent: 5182247 (1993-01-01), Kuhlmann et al.
patent: 5321195 (1994-06-01), Travers et al.

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