Continuous process for preparing aluminum alkyls and linear 1-ol

Details Continuous process for preparing aluminum alkyls and linear 1-ol Continuous process for preparing aluminum alkyls and linear 1-ol

1991-08-02

1993-03-02

Dees, Jose G.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

By double-bond-shift isomerization

585664, 585669, 585671, 556187, 556190, C07C 525, C07C 523, C07F 506

Patent

active

051911450

ABSTRACT:
Linear 1-olefins are continuously prepared from internal olevins by (i) continuously feeding internal olefin, isomerization catalyst and tri-lower alkyl aluminum to a reaction zone so as to cause the internal olefin to isomerize to 1-olefins which displace the lower alkyl groups to form a trialkyl aluminum compound in which at least one of the alkyl groups is a linear alkyl derived from the 1-olefin, (ii) continuously removing trialkylaluminum compound from the reaction zone and, thereafter, (iii) reacting the trialkyl aluminum compound with a 1-olefin so as to displace the linear alkyl from the trialkyl aluminum compound, thereby forming a linear 1-olefin product which is substantially free of internal olefins.

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