Continuous process for preparing alkanolamines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564475, C07C 8500, C07C 8502, C07C 8900, C07C 8902

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048474185

ABSTRACT:
A continuous process is provided for preparing alkanolamines having a high yield of monoalkanolamine, which comprises continuously reacting a flowing stream of a homogeneous mixture of an alkylene oxide having from two to four carbon atoms and ammonia in a molar ratio of ammonia to alkylene oxide within the range from about 15:1 to about 50:1 at temperatures above the critical temperature of the mixture and at pressures above the critical pressure of the mixture and maintaining the mixture in a single phase having a density of at least 15 lbs./cu.ft. for the time necessary to form an alkanolamine product mixture containing at least about 65% by weight monoalkanolamine.

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patent: 3544632 (1970-12-01), Haarer et al.
patent: 3697598 (1972-10-01), Weibull
patent: 3723530 (1973-03-01), Goetze et al.
Batten, Chemical Abstracts, vol. 73, #36865g (1970).

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