Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Partial
Reexamination Certificate
1995-07-06
2002-02-05
Yildirim, Bekir L. (Department: 1764)
Chemistry of hydrocarbon compounds
Adding hydrogen to unsaturated bond of hydrocarbon, i.e.,...
Partial
C585S269000, C585S271000
Reexamination Certificate
active
06344593
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an improved process for the continuous preparation of cyclohexene by partial hydrogenation of benzene with hydrogen in the presence of water and a ruthenium catalyst at elevated temperatures and superatmospheric pressure.
2. Description of Related Art
U.S. Pat. No. 4,678,861 describes the batchwise partial hydrogenation of benzene to cyclohexene in a suspension, the reaction being carried out in a two-phase, liquid mixture. The disadvantage of this procedure is the separation of the catalyst from the organic phase and possibly the discharge of salts.
EP-A 552 809 describes the partial hydrogenation of benzene to cyclohexene in a system consisting of an aqueous phase, containing the catalyst suspended therein, an oily phase, containing the hydrocarbon to be hydrogenated, and a gaseous phase comprising hydrogen. One of the disadvantages of this procedure is the fact that the reaction has to be interrupted in order to separate the organic phase from the aqueous phase.
EP-B 55 495 describes the partial hydrogenation of benzene to cyclohexene in the gas phase, the maximum cyclohexene yield achieved being only 8.4%.
It is an object of the present invention to provide an improved process for the continuous preparation of cyclohexene by partial hydrogenation of benzene with hydrogen in the presence of water and a ruthenium catalyst at elevated temperatures and superatmospheric pheric pressure, which does not have the abovementioned disadvantages.
SUMMARY OF THE INVENTION
We have found that this object is achieved by a process for the continuous preparation of cyclohexene by partial hydrogenation of benzene with hydrogen in the presence of water and a ruthenium catalyst at elevated temperatures and superatmospheric pressure, wherein benzene is introduced in gaseous form and the resulting cyclohexene is discharged in gaseous form, the catalyst being present in solution or suspension in a liquid, aqueous phase.
DESCRIPTION OF PREFERRED EMBODIMENTS
According to the invention, benzene and hydrogen, together or separately, are introduced in gaseous form and the resulting cyclohexene is discharged in gaseous form. Advantageously, benzene is introduced into the reaction space together with an inert gas as a carrier, the inert gas, such as nitrogen, helium or argon, preferably being passed through a benzene-containing saturation apparatus, benzene being absorbed in gaseous form. Usually, the loading of the inert gas stream is effected at from 20 to 250° C., preferably from 50 to 170° C., the inert gas preferably being heated for this purpose upstream of the saturation apparatus. The pressure downstream of the saturation apparatus is advantageously chosen so that it corresponds to the total pressure in the reaction space.
When an inert gas is us d as a carrier gas for benzene, the benzene concentration is usually chosen to be from 0.1 to 99.9, preferably from 0.5 to 95, % by volume.
According to the invention, the gaseous benzene, with or without the carrier gas, is fed to the hydrogenation catalyst, which is present in dissolved or suspended form in a liquid, aqueous phase. The benzene partial pressure and the reaction space is generally chosen to be from 10 kPa to 1 MPa, preferably from 150 kPa to 0.5 MPa.
Observations to date have shown that the gaseous benzene can be fed into the reaction space by various methods, for example with or without a nozzle, via a simple inlet tube, into the liquid, aqueous phase or above the liquid surface.
The hydrogen partial pressure in the reaction space is chosen, as a rule, to be from 50 kPa to 5 MPa, preferably from 0.5 MPa to 4 MPa.
The reaction is advantageously carried out at from 20 to 300° C., preferably from 100 to 200° C.
The pressure and temperature conditions are advantageously co-ordinated with one another to ensure that a liquid, aqueous phase 35 is maintained and that the amount of benzene introduced corresponds to the amount of organic material discharged, consisting essentially of cyclohezene, cyclohexane and unconverted benzene. In a preferred embodiment, the pressure in the reaction space is controlled by means of an inert gas, such as nitrogen, argon or helium, preferably nitrogen, the total pressure in the reaction space being chosen to be from 0.1 to 20, preferably from 1 to 10, MPa.
The liquid, aqueous phase is advantageously agitated, preferably by stirring, the stirring speeds being chosen to be from 300 to 1500, preferably from 750 to 1500, revolutions per minute.
Observations to date have shown that all known ruthenium-containing homogeneous or suspension catalysts (supported catalysts or precipitated catalysts) may be used as catalysts. Such catalysts are described, for example, in U.S. Pat. No. 4,678,861, EP-A 220,525, WO 93/16971, WO 93116972 and EP-A 554,765, catalysts prepared according to Example 1 from U.S. Pat. No. 4,678,861 (ruthenium on a lanthanum oxide carrier) and Example 1 from EP-A 220,525 (ruthenium/zinc precipitated catalysts) and according to Example 1 from DE-A 4,203,220 (ruthenium
ickel precipitated catalysts) being particularly preferred.
A catalyst which contains from 0.01 to 100, preferably from 0.1 to 80, % by weight, based on benzene used, of ruthenium is advantageously employed.
According to the invention, the reaction is carried out in the presence of water. The weight ratio of water to catalyst is preferably chosen to be from 5:1 to 1000:1, particularly preferably from 50:1 to 500:1.
In general, water is introduced into the reaction space at the rate at which water is discharged in gaseous form, and the water may be introduced in liquid form by means of pumps or in gaseous form, for example via a saturation apparatus.
Benzene and, if desired, inert gas are advantageously added in amounts such that the catalyst is always present completely in the aqueous phase.
The reaction may be carried out in the alkaline, neutral or acidic range, depending on the catalyst system.
When the reaction is carried out in an alkaline medium, as a rule hydroxides of alkali metals or alkaline earth metals, particularly preferably sodium hydroxide or potassium hydroxide, in an amount of from 0.01 to 10, preferably from 0.1 to 5, mol/l, are added to the aqueous phase.
When the reaction is carried out in an acidic medium, as a rule acidic salts of transition metals or inorganic or organic acids, in an amount of from 0.001 to 10, preferably from 0.1 to 5, mol/l are added to the aqueous phase.
The aqueous phase advantageously contains one or more dissolved cations of transition metals of Groups 2 to 8 of the Periodic Table, such as chromium, manganese, iron, cobalt, copper or zinc, and ammonium in the form of their chlorides, nitrates, acetates, phosphates or sulfates. The amount of metal malt is advantageously from 0.01% by weight to the saturation concentration, based on the aqueous phase.
It may furthermore be advantageous to add at least one of the metal oxides selected from the group consisting of alumina, silica, zirconium dioxide, titanium dioxide, hafnium dioxide, chromium trioxide and zinc oxide to the reaction mixture. The amount of metal oxide added is preferably from 0.001 to 1% by weight, based on the amount of water used.
The discharged gas mixture, which contains essentially cyclohexene, cyclohexane, unconverted benzene and hydrogen and may contain inert gas, is generally worked up by distillation, for example by separating the organic phase by condensation from the rest of the mixture and then obtaining cyclohexene therefrom by extractive distillation.
In a preferred embodiment, a conventional stirred kettle is used for carrying out the reaction. By connecting a plurality of stirred kettles in series, flow tube behavior can be achieved. Observations to date have shown that other reactor types, such as bubble column reactors, may also be used.
The cyclohexene obtainable by the novel process is suitable for the preparation of cyclohexanol, an important starting material for the production of fiber intermediates.
The advantages of t
Doebert Frank
Gaube Johann
Keil & Weinkauf
Yildirim Bekir L.
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