Continuous on-line process control of residua distillation

Chemistry: analytical and immunological testing – Geochemical – geological – or geothermal exploration – For petroleum oils or carbonaceous minerals

Reexamination Certificate

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C436S050000, C436S055000, C436S149000

Reexamination Certificate

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10374779

ABSTRACT:
Ultrasonic spectroscopy, calorimetry, or thermogravimetric analysis provide measures which correlate with properties of asphaltene complex of petroleum residua which can be used to establish or maintain consistent properties of petroleum residua during blending or to determine immediacy of petroleum residuea to deposition phenomena during pyrolytic thermal treatment.

REFERENCES:
patent: 4493765 (1985-01-01), Long et al.
patent: 4628204 (1986-12-01), Maes
patent: 4990773 (1991-02-01), Supernaw et al.
patent: 5092983 (1992-03-01), Eppig et al.
patent: 5574215 (1996-11-01), Bunger et al.
patent: 5861228 (1999-01-01), Descales et al.
patent: 5969237 (1999-10-01), Jones et al.
patent: WO 00/77120 (2000-12-01), None
Carrier et al. “Acoustic method for measuring asphaltene flocculation in crude oils”, Journal of Petroleum Science & Engineerin (2000), 27(3-4), 111-117.
Chambers et al. Bondline Analysis Using Swept-Frequency Ultrasonic Spectroscopy http://www.southernresearch.org/uspec/Insight0399 PDF, 092/04/1999.
Schabron et al. “Coking indexes using the Heithaus titration and asphaltene solubility”, Preprints—American Chemical Society, Division of Petroleum Chemistry (1999), 44(2), 187-189.
Jones et al. “Development of an ultrasonic oil stability monitor for the assessment of asphaltene aggregation in hydrocarbon streams”, Proceed. Intern. Conf. Mitigat. Heat Exch. Foul. Econ. Envir. Implic. Banff, AB, Canada, Jul. 1999, 84-94.
Andersen, S.I. and K.S. Birdi, 1991, “Aggregation of Asphaltenes as Determined by Calorimetry,”Journal of Colloid and Interface Science, 142, 497-502 1991.
Barton, A.F., 1974, “Solubility Parameters.” 1974Chemical Reviews, 75 (6), 731-753.
Burrell, H., 1955, “Solubility Parameters.” Spring, 1955,Interchemical Review, 3-16.
“Energy and Environmental Profile of the U.S. Petroleum Refining Industry,” 1998, Prepared by Energetics Inc. for U.S. Department of Energy Office of Industrial Technologies, pp. 4-5, 27, 33, 49, and 62-63.
Heithaus, J. J., 1962, “Measurement and Significance of Asphaltene Peptization.” Journal of the Institute of Petroleum 48 (458), 45-53.
Hildebrand, J.H., J.M. Prausnitz. and R.L. Scott, 1970, “Regular and Related Solutions,” Van Nostrand Reinhold, NY, pp. 24-27, pp. 152-153, pp. 212-215.
Long, R.B. and J.G. Speight, 1989, “Studies in Petroleum Composition,”Revue de Institute Francais du Petrole, 44 (2), 205-217.
Long R.B., 1979, “The Concept of Asphaltenes,”Preprints, Div. Petroleum Chemistry, American Chemical Society, 24, 891-901.
Magaril, R.Z., E.I. Aksenova, 1968, “Study of the mechanism of Coke Formation in the Cracking of Petroleum Resins,” International Chemical Engineering (vol. 8, No. 4), 1 page.
Pauli, A.T., 1996 “Asphalt Compatibility Testing Using the Automated Heithaus Titration Test,”Preprints, Division of Fuel Chemistry, American Chemical Society, 41 (4), 1276-1281.
Scatchard, G., 1931, “Equilibria in Non-Electrolyte Solutions in Relation to the Vapor Pressure and Densities of the Components,”Chemical Reviews, 321-333.
Schabron, J.F., A. Troy Pauli, Joseph F. Rovani, Jr., Francis P. Mikins, 2000 “Deposition from Heavy Oils,” Department of Energy Report DE-FC26-98FT40322, 35 pages.
Schabron, J.F., A Troy Pauli, Joseph F. Rovani, Jr., 2001 “Molecular Weight Polarity Map for Residua Pyrolysis” Fuel 80 529-537.
Schabron, J.F., A. Troy Pauli, Joseph F. Rovani, Jr., 2001 “Non-pyrolytic Heat Induced Deposition from Heavy Oils,” Fuel 80 919-928.
Schabron, J.F., A. Troy Pauli, Joseph F. Rovani, Jr., Francis P. Mikins, 2001, “Predicting Coke Formation Tendencies,” Fuel 80 1435-1446.
Schabron, J.F., A. Troy Pauli, Joseph F. Rovani, Jr., 1999 “Petroleum Residua Solubility Parameter/Polarity Map: Stability Studies of Residua Pyrolysis,” Department of Energy Report DE-FC26-98FT40322 Task, 1.2, 24.
Schabron, J.F., and J. G. Speight, 1998, “The Solubillity and Three-Dimensional Structure of Asphaltenes,”Petroleum Science and Technology, 16 (3-4), 361-376.
Schabron, J.F., G. W. Gardner, J.K. Hart, N.D. Niss, Miyake, and D.A. Netzel, 1993, “The Characterization of Petroleum Residua,” US Department of Energy Report DE-MC/11076-3539, 9 pages.
Schabron, J.F., J.R. Rovani, Jr., T.F. Turner, 2002, “Thermal Analysis for Monitoring Incipient Coke Formation”, US Department of Energy Report DE/FG36/01G011018, 18 pages.
Small, P.A., 1953, “Some Factors Affecting the Solubility of Polymers”Journal of Applied Chemistry, 71-80.
Snyder, L.R., 1968, “Principles of Adsorption Chromatography”, Marcel Dekker, Inc., New York, 206-210.
Wiehe, I.A., 1996, “Two-Dimensional Solubility Parameter Mapping of Heavy Oils,”Fuel Science and Technology International, 14 (1&2), 289-312.
“Standard Test Method for Molecular Weight (Relative Molecular Mass) of Hydrocarbons by Thermoelectric Measurement of Vapor Pressure,” ASTM Designation: D 2503—82 (Reapproved 1987), 211-213.
David Julian McClements, “Ultrasonic Measurements in Particle Size Analysis”, University of Massachusetts, Amherst, USA,Encyclopedia of Analytical Chemistry(Applications, Theory and Instrumentation) pp. 5581-5587.
Waterman, P.C. Truell, Rohn, “Multiple Scattering of Waves”, Journal of Mathematical Physics, Jul.-Aug., 1961, pp. 512-537.
Cartz, Louis, ch. 3, “Ultrasonic Testing”, Nondestructive Testing, 1995, pp. 81-98.
Schabron, John F., et al., “Characterization of Residua During Pyrolysis”, American Chemical Society, vol. 47, No. 1, Feb. 2002, pp. 17-21.
Ulrich Riebel, Loffler, Friedrich, “The Fundamentals of Particle Size Analysis by Means of Ultrasonic Spectrometry”, Part. Part. Syst. Charact. 6, 1989, pp. 135-143.
Povey, Malcolm J. W., “Ultrasonic Techniques for Fluids Characterization” 1997.
Kaatze, U., et al., “Acoustical Absorption Spectroscopy of Liquids Between 0.15 and 3000 MHz: I. High Resolution Ultrasonic Resonator Method”, J. Phys. E: Sci. Instrum. 1988, pp. 1025-1030.
Kaatze, U, et al., “Acoustical Absorption Spectroscopy of Liquids Between 0.15 and 3000 MHz: II. Ultrasonic Pulse Transmission Methods”, J. Phys. E: Sci. Instrum. 1986, pp. 98-103.
Kaatze, U., et al., “Acoustical Absorption Spectroscopy of Liquids Between 0.15 and 3000 MHz: III. Hypersonic Comparator Technique”, J. Phys. E: Sci. Instrum. 1987, pp. 402-406.
Kaatze, U., et al. “Broadbond Study of the Scattering of Ultrasound by Polystyrene-latex-in-water Suspsnsions” Annalen der Physik, 1996, pp. 13-33.
Schabron, John F., “The Solubility and Three-Dimensional Structure of Asphaltenes”, Petroleum Science and Technology, 16(3&4), 1998, pp. 361-375.
McClements, David Julian, “Ultrasonic Characterization of Emulsions and Suspensions”, Advances in Colloid and Interface Science, 37, 1991, pp. 33-72.
Challis, Richard E., et al., “A Wide Bandwidth Spectrometer for Rapid Ultrasonic Absorption Measurements in Liquids”, Journal of the Acoustical Society of America, vol. 90, No. 2, Pt. 1, Aug. 1991, pp. 730-740.
Epstein, Paul S., et al., “The Absorption of Sound in Suspensions and Emulsions. I. Water Fog in Air”, Journal of the Acoustical Society of America, vol. 25, No. 3, May 1953, pp. 553-565.
Allegra, J. R., et al., “Attenuation of Sound in Suspensions and Emulsions: Theory and Experiments”, Journal of the Acoustical Society of America, vol. 51, No. 5, pt. 2, pp. 1545-1564.
Hemar, Y., et al., Effective Medium Model for Ultrasonic Attenuation Due to the Thermo-Elastic Effect in Concentrated Emulsions, Journal De Physique II, Apr. 1997, pp. 637-647.
McClements, D. J., et al., “Scattering of Ultrasound by Emulsions”, J. Phys. D: A

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