Continuous-flow free acid monitoring method and system

Chemistry: physical processes – Physical processes – Crystallization

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Details

23232R, 23232E, 23230A, 422 90, 422 62, 422 81, G01N 2710, G01N 2706

Patent

active

042722470

ABSTRACT:
A free acid monitoring method and apparatus is provided for continuously measuring the excess acid present in a process stream. The disclosed monitoring system and method is based on the relationship of the partial pressure ratio of water and acid in equilibrium with an acid solution at constant temperature. A portion of the process stream is pumped into and flows through the monitor under the influence of gravity and back to the process stream. A continuous flowing sample is vaporized at a constant temperature and the vapor is subsequently condensed. Conductivity measurements of the condensate produces a nonlinear response function from which the free acid molarity of the sample process stream is determined.

REFERENCES:
patent: 2949345 (1960-08-01), Clauss
patent: 3367747 (1968-02-01), Sieth et al.
patent: 3904365 (1975-09-01), Larson et al.
patent: 3915646 (1975-10-01), Harris et al.

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