Continuous electrolytic production of alkali metal perchlorates

Chemistry: electrical and wave energy – Processes and products

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204 95, C25B 126, C25B 128

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active

050045270

ABSTRACT:
The alkali metal perchlorates, e.g., sodium perchlorate or hydrate thereof, are continuously produced by continuously electrolyzing an aqueous solution electrolyte of a corresponding alkali metal chlorate in a single stage, while maintaining such electrolyte homogeneous and compositionally uniform over time by the continuous and simultaneous introduction of alkali metal chlorate and water thereto, and continuously directly separating desired alkali metal perchlorate from such solution of electrolysis.

REFERENCES:
patent: 2512973 (1950-06-01), Schumacher
patent: 3475301 (1969-10-01), Cook, Jr. et al.
patent: 3518173 (1970-06-01), Crane
patent: 3518180 (1970-06-01), Grotheer
patent: 4144144 (1979-03-01), Radimer et al.
patent: 4267025 (1981-05-01), de Nora et al.
Pascal, "New Treatise on Inorganic Chemistry", vol. II, No. 1, (1966), p. 353 and FIG. 37.

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