Container and reference electrode for use in radiated aqueous en

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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204279, 204286, 204297R, 204400, 22826311, 22826312, 376245, 376256, G01N 2730

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active

051189135

ABSTRACT:
A container for electrochemical reactants for an electrode is provided, as well as electrodes employing the same. The electrodes can withstand the rigorous environment of a nuclear reactor core. The design of the container reduces stresses in the electrode and significantly improves its reliability. The container has a generally cylindrical member of an insulator. The member has a base region whose outer surface is a surface attachment region. The base region has an annular channel for a lead. The base region also has a generally conical cut-out. Sidewall means extend from said base to define a cavity for containing electrochemical reactants, e.g., silver chloride. A generally conical insert of an insulator mates with the cut-out. The outer surface of the insert, cut-out, and surface attachment region is metallized, and the insert is set in place by brazing. In the electrode the lead is in electrical contact with the apex of the insert.

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Vermilyea et al., J. Electrochem. Soc., vol. 119, No. 1, (Jan. 1972), pp. 39-43.

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