Conjugate addition

Details Conjugate addition Conjugate addition

1973-12-18

1976-01-27

Weinberger, Lorraine A.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260268R, 26029369, 26029371, 26029375, 26029378, 260295R, 260307F, 2603262, 26032662, 2603268, 260465E, 260468J, 260482R, 424248, 424250, 424267, C07D29500

Patent

active

039352072

ABSTRACT:
Organic compounds are prepared by a novel method of conjugate addition in which a donor compound including a carbanion derived from an activated methylidyne group is treated with an acceptor compound including a carbon-carbon unsaturated bond conjugated with an onium ion derived from a polar functional group. The method has particular application as a step in the production of novel intermediates and novel pharmacologically active compounds as disclosed in the Applicants' co-pending application of even date.

REFERENCES:
adams et al., Organic Reactions, Vol. 10, pp. 182-183, (1959).
Dimroth et al., Chem. Ber. 90, 2207 (1957).

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