Compositions – Electrically conductive or emissive compositions – Metal compound containing
Patent
1992-02-14
1993-11-09
Lieberman, Paul
Compositions
Electrically conductive or emissive compositions
Metal compound containing
252500, 430 63, 430 64, 106 122, 106 126, 427101, 427226, 427229, H01B 100
Patent
active
052599922
ABSTRACT:
Conductivizing coating solutions prepared from cuprous iodide and ligands which are pyridine or monodentate pyridine derivatives provide excellent transparent, conductive coatings for use in electrophotographic and ground plane including articles. The coating compositions may also utilize solvents which solubilize the cuprous iodide-ligand complex formed. A method of forming transparent conductivizing coating solutions is also provided.
REFERENCES:
patent: 3245833 (1966-04-01), Trevoy
patent: 3597272 (1971-08-01), Gramza et al.
patent: 3740217 (1973-06-01), Gramza et al.
patent: 4122143 (1978-10-01), Momotari et al.
patent: 5063128 (1991-11-01), Yuh et al.
Vogler et al, "Photoluminescence of Tetrameric Copper (I) Iodide Complexes" J. Am. Chem. Soc., (1986), 108, pp. 7211-7212.
Raston et al. "Crystal Structure of the Copper(I) Iodide-Pyridine (1/l) Tetramer", J. C. Dalton (1976), pp. 2153-2156.
Lindemann et al, "Kurze Originalmitteillungen", Naturwissenschaften 61, Sringer-Verlag, (1974), pp. 500-501.
Davies et al, "Homogeneous Oxidative Coupling Catalysts", Advances in Chemistry Series, No. 173, Inorganic Compounds with Unusual Properties, II, (1979), pp. 178-194.
Davies et al, "A Spectrophotometric Study of the Reactions of the Phenolic Oxidative Coupling Initiator py.sub.4 Cu.sub.4 Cl.sub.4 O.sub.2 and of py.sub.4 Cu.sub.4 Cl.sub.6 O with Pyridine", Inorganica Chimica Acta, 71 (1983), pp. 95-99.
Karlin et al, "Dioxygen-Copper Reactivity: Generation, Characterization, and Reactivity of a Hydroperoxo-Dicopper(II) Complex", J. Am. Chem. Soc. (1988), 110, pp. 6769-6780.
Dietrich-Buchecker et al, "Bis(2,9-diphenyl-1, 10-phenanthroline)copper(I): a Copper Complex wtih a Long-lived Charge-transfer Excited State", J. Chem. Soc., Chem. Commun., (1983), pp. 513-515.
Floriani et al, "Aggregation of Metal Ions with Functionalized Calixarenes: Synthesis and Structue of an Octanuclear Copper(I) Chloride Complex", Angew. Chem. Int. Ed. Engl. 28, (1989), No. 10, pp. 1376-1377.
Vogler et al, "Copper(I)-Assisted Formation of an Organic" Sandwich Structure: Structural Prerequisites for Luminescence of the Dinuclear Complexes[(.mu.-Bipyrimidine) {Cu(PR.sub.3).sub.2 }]X.sub.2, Angew. Chem. Int. Ed. Engl. 28 (1989), No. 12, pp. 1659-1660.
Gol et al, "[Cu.sub.8 (iPrPCH.sub.2 PiPR).sub.2 Cl.sub.4 (py).sub.5 ], a Novel Cu Cluster Containing Pentacoordinated Phosphorus in .mu..sub.3 -PRR' Bridges (R=iPR, R'=CH.sub.2 PiPr)", Angew. Chem. Int. Ed. Engl. 27 (1988), No. 7, pp. 956-957.
Scattergood et al, "Synthesis and Characterisation of [VS.sub.4 (CuPPh.sub.3).sub.5 (CuCl)Cl.sub.2 ]. CH.sub.2 Cl.sub.2 ; a Compound containing a Tetrahedral V'S.sub.4 Core Encapsulated by an Octahedral Array of Copper(I) Atoms", Journal of Chemical Society, No. 23, (1987), pp. 1749-1750.
Wheland et al, "Synthesis of Electrically Conductive Organic Solids", Journal of the American Chemical Society, 98:13, (1976), pp. 3916-3925.
Kyle et al, "Dynamic Quenching of the Metal-to-Ligand Charge-Transfer Excited State of Cu.sub.4 I.sub.4 (pyridine).sub.4 Exciplex Formation and Self-Quenching", Journal of the American Chemical Society, (1989), 111, pp. 5005-5006.
Kyle et al, "Dual Photoemissions from the Room Temperature Solutions of the Tetranuclear from the Room Temperature Solutions of the Tetranuclear Copper(I) Clusters Cu.sub.4 I.sub.4 (py-X=Substituted Pyridine)", Journal of Chemical Society, Chem. Commun., (1989), pp. 714-715.
Lehn et al, "Helicates: Tetra-and Pentanuclear Double Helix Complexes of Cu.sup.I and Poly(bipyridien) Strands", Angew. Chew. Chem. Int. Ed. Engl. 27 (1988) No. 8, pp. 1095-1097.
Biagini et al, "Ligand Lability in and Electron Trnsfer of [CO(py).sub.6 ]+; Cyclotrimerisation of alkynes and Synthesis, Structure, and Properties of (.eta..sub.6 -C.sub.6 Ph.sub.6)CO(.eta..sup.2 -C.sub.2 Ph.sub.2 (py=pyridine)", J. Chem. Soc. Chem. Commun., (1989), pp. 405-407.
Vogler et al, "Photoluminescence of Tetrameric Copper(I) Iodide Complexes in Solution," J. Am. Chem. Soc., (1986), 108, pp. 7211-72712.
G, Tartarini, "Nuove reazioni cromatiche dei sali rameosi-Nota preliminare." Gazzetta Chimica Italina, vol. LXIII, (1933), pp. 597-601.
Tompkins et al, "Solid State Structures of Nonemitting Complexes of Cuprous Iodide: (CuI(methylquinaldate).sub.x (I), (CuI(isopropylquinaldate)).sub.2 (III) and (CuI(n-butylquinaldate)).sub.2 (III)", Inorganica Chimica Acta, 127 (1987), pp. 1-7.
Eitel et al, "Structural Isomers of Coper(I) Iodide Pyridine and their Luminescence Properties, Synthesis and Crystal Structure of a New Modification of CuI NC.sub.5 NC.sub.5 H.sub.5 ", Z. Naturforsch (1980), pp. 1247-1253.
Davies et al, "Stoichiometery and Kinetics of the Oxidation of Halo(pyridine) copper(I) Complexes by Dioxygen in Aprotic Solvents. Effects of Copper(I) Reactant Molelcularity on the Rate Law and Evidence for Ligand-Dependent Product Structures", Inorganic Chemistry, (1983), vol. 22, No. 9, pp. 1257-1267.
Caulton et al, "Synthesis, Molecular Strucutures, Properties and Reactions of Halo and Carbonyl(Amine)Copper(I) Complexes", Polyhedron, (1990), vol. 9, No. 19, pp. 2319-2351.
Malik, "Co-ordination Compounds of Cuprous Iodide with Heterocyclic Amines", J. Inorg. Nucl. Chem. (1967), vol. 29, pp. 2106-2107.
Chow et al, "Nonaromatic Aminium Radicals", Chemical Reviews, (1978), vol. 78, No. 3, pp. 243-274.
Stolle et al, "Transparent Conductive Cuprous Iodide Layer", Chemical Abstracts, 95:195185f, vol. 95, (1981), p. 564.
Shinonome et al, "Cuprous Iodide-Containing Polymer Compositions for Electric Conductive for Coatings" Chemical Abstracts, 111:98491 1, (1989), p. 3.
Kopec M.
Lieberman Paul
Rexham Graphics Inc.
LandOfFree
Conductivizing coating solutions and method of forming conductiv does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Conductivizing coating solutions and method of forming conductiv, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Conductivizing coating solutions and method of forming conductiv will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1140720