Concentration and purification of plutonium or thorium

Chemistry: electrical and wave energy – Processes and products

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204253, C01G 5600, C25C 122

Patent

active

039487350

ABSTRACT:
In this invention a first solution obtained from such as a plutonium/thorium purification process or the like, containing plutonium (Pu) and/or thorium (Th) in such as a low nitric acid (HNO.sub.3) concentration may have the Pu and/or Th separated and concentrated by passing an electrical current from a first solution having disposed therein an anode to a second solution having disposed therein a cathode and separated from the first solution by a cation permeable membrane, the Pu or Th cation permeating the cation membrane and forming an anionic complex within the second solution, and electrical current passage affecting the complex formed to permeate an anion membrane separating the second solution from an adjoining third solution containing disposed therein an anode, thereby effecting separation and concentration of the Pu and/or Th in the third solution.

REFERENCES:
patent: 3086925 (1963-04-01), Didchenko et al.
patent: 3272726 (1966-09-01), Gibson et al.
patent: 3821091 (1974-06-01), Bilal et al.

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