Concentrated sulphuric acid treatment of an alkylphenyl acid pho

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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210634, 423 8, C01G 4300

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043850375

ABSTRACT:
Uranium in wet-process phosphoric acid in the tetravalent state is extracted with an alkylphenyl acid phosphate extractant comprising a mixture of mono- and di(alkylphenyl) esters of orthophosphoric acid. The pregnant extractant is stripped with a suitable stripping solution, and the barren extractant recycled to the extractant step. At least a portion of the recycled extractant is treated with concentrated sulphuric acid to remove organic and inorganic impurities including alkylphenol present in the barren extractant as a result of hydrolysis from the mixture of mono- and di-(alkylphenyl) esters of orthophosphoric acid to regenerate the extractant.

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Murphy et al., "Study of Some Phenyl Phosphonic Acids for Extractor of Uranium from Phosphoric Acid," IAEA-SM-135/11, pp. 341-350.
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