Compounds useful as stabilizing agents for rubber vulcanizates

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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524106, 524170, 524208, 524289, 524223, 524303, 524357, 524393, 548376, 560145, 560152, 560153, 560154, 564154, 568 31, 568 42, 568 43, 568 56, 568477, 568413, 556114, 556131, 556149, C08K 541, C08K 536, C07C14926, C07C14914, C07D40312

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046579567

ABSTRACT:
Additives for rubber compositions, giving vulcanizates having improved retention of optimum physical properties, are compounds having the formula R--S--B--S--R where B is an organic bridging group and R is an electron-withdrawing group, for example CN, CCl.sub.3, a radical containing an activated methylene group linked to the sulphur atom or the enolic tautomer of a keto-activated methylene group. Also useful as stabilizing agents are oligomeric analogues of such compounds.

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Yoshida: Tetrahedron, 26 (12) 2987-93 (1970).
Chemical Abstracts 33:5825-7, "Polymethylenebisthionylacetic Acid," Erik Larsson.
Chemical Abstracts 39:1586-4, "Complex Compounds Between Ag and Some S-Containing Carboxylic Acid Ions in Aqueous Solution," Erik Larsson.
"Studies on Antitumor Substances IX," Chemical Behaviors of Thiosulfonate Toward Active Methylene Compound, Seigoro Hayashi et al, Chemical & Pharmaceutical Bulletin, vol. 17, No. 3, Mar. 1969.

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