Compounds of o-(6-hydroxy-3-oxo-3H-thio(seleno)xanthen-9-yl)benz

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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549 26, 549388, C07D49500, C07D51700

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045826412

ABSTRACT:
Compounds of the formula ##STR1## wherein R.sup.1 -R.sup.4 is hydrogen or chlorine, R.sup.5 is --COOMe or --SO.sub.3 Me, Me is an alkali metal cation and X is oxygen, sulfur or selenium,
photosensitizers for the conversion of tachysterol into previtamin D are described. The tachysterol content in mixtures of previtamin D and tachysterol can be greatly reduced by UV-irradiation in the presence of such photosensitizers.

REFERENCES:
patent: 1532790 (1925-04-01), Weiler
patent: 2157351 (1939-05-01), Schneider et al.
patent: 3539590 (1970-11-01), Oftedahl
J.C. S. Chem. Comm. "Photolytic Production of Vitamin D, The Preparative Value of a Photo-Sensitiser", S. Eyley, D. Williams, p. 858 (1975).
Nouveau Journal de Chimie, "Photosensitized Isomerization of Previtamin D.sub.2 and Tachysterol and the Related 1,2-Bis-(1-Cyclopentenyl) Ethylene: Torsional Potential Curves of Triene Triplets", M. Denny, R. Liu, vol. 2, No. 6, pp. 637-641.

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