Compounds derived from L a2 Mo 2 O 9 and their use as ionic...

Compositions – Electrically conductive or emissive compositions

Reexamination Certificate

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C252S518100, C252S520200, C252S521100, C252S521200, C429S010000, C423S606000, C501S046000

Reexamination Certificate

active

07018566

ABSTRACT:
The invention concerns novel compounds derived from La2Mo2O9and their use as ion conductors.The compounds of the invention have formula (1):in-line-formulae description="In-line Formulae" end="lead"?A2−xA′xB2−yB′yO9−z+δXzin-line-formulae description="In-line Formulae" end="tail"?in which A is at least one trivalent element selected from trivalent rare earths, trivalent bismuth, trivalent antimony and trivalent arsenic; A′ is at least one monovalent element selected from alkalis; or a divalent element selected from alkaline-earths, tin, lead, samarium, europium, erbium, thulium and ytterbium; or a quadrivalent element selected from thorium, uranium, group IVA elements, cerium, praseodymium and terbium; B is at least one hexavalent element from groups VIA, VIIA, VIII and group VIB with the exception of oxygen; B′ is at least one element selected from lithium, sodium, magnesium, calcium, scandium, yttrium, rare earths with atomic numbers 63 to 71, elements from groups IVA to IIB with an oxidation number of less than 6, aluminium III, silicon IV, gallium III, germanium IV, indium III, tin IV, phosphorus V, antimony V and bismuth V; X is selected from sulphur, fluorine and chlorine; where 0≦x<2; 0≦y<2; 0≦z≦3; and with the condition that when A is lanthanum and B is tungsten or molybdenum, at least one of x, y or z is different from 0; the compounds having a cationic cubic or pseudo-cubic β-SnWO4type lattice.

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International Search Report.

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