Compounds and methods for doping liquid crystal hosts

Compositions – Liquid crystal compositions – Containing pleochroic dye

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

2522992, 252582585, 349196, 549 53, 549 54, 549 55, 549 56, C09K 1960, G02F 1137, C07D33364, F21V 914

Patent

active

059894512

ABSTRACT:
This invention provides chiral thioindigo compounds for doping smectic liquid crystal hosts, wherein the compounds modulate a chiral bulk property of an induced chiral smectic liquid crystal phase upon irradiation at a wavelength in the visible range. Modulation of the chiral bulk property is effected by reversible trans-cis photoisomerization of the compound upon irradiation. The compounds maintain their rod-like shape in both isomeric forms, and hence do not destabilize the chiral smectic liquid crystal phase. Compounds according to the invention are useful in optical devices such as optical switches, displays, and memory.

REFERENCES:
patent: 4712874 (1987-12-01), Sekimura et al.
patent: 4778619 (1988-10-01), Wakemoto et al.
patent: 5026505 (1991-06-01), Kaneko et al.
patent: 5078475 (1992-01-01), Sekimura et al.
patent: 5118586 (1992-06-01), Hattori et al.
patent: 5212575 (1993-05-01), Kojima et al.
patent: 5240797 (1993-08-01), Matsushima et al.
patent: 5242558 (1993-09-01), Matsushima et al.
patent: 5278009 (1994-01-01), Iida et al.
patent: 5296952 (1994-03-01), Takatsu et al.
patent: 5364668 (1994-11-01), Takimoto et al.
patent: 5368991 (1994-11-01), Uchikawa et al.
patent: 5395678 (1995-03-01), Matsushima et al.
patent: 5443864 (1995-08-01), Takimoto et al.
patent: 5461494 (1995-10-01), Sekimura et al.
patent: 5486442 (1996-01-01), Takimoto et al.
patent: 5486936 (1996-01-01), Fujikake et al.
patent: 5520855 (1996-05-01), Ito et al.
patent: 5602660 (1997-02-01), Sekimura et al.
patent: 5650867 (1997-07-01), Kojima et al.
Collins-Gold, L., et al., "Interfacial effects on excited-state potential energy surfaces. Interrelationship between photoreactivity and surface properties", Langmuir 2:191-194 (1986).
Dinescu, L. et al., "Modulating the spontaneous polarization of a ferroelectric liquid crystal via the photoisomerization of a chiral thioindigo dopant: (R,R)-6,6'-bis(1-methylheptyloxy)thioindigo", Liq. Cryst., 20:741-749 (1996).
Dinescu, L. et al., "Photomodulating the spontaneous polarization of a ferroelectric liquid crystal phase using chiral thioindigo dopants", SPIE vol. 3015.multidot.0277-786X/97.
Dinescu, L. et al., "Photomodulation of the spontaneous polarization of a ferroelectric liquid crystal: harnessing the transverse dipole modulation of a chiral thioindigo dopant", J. Am. Chem. Soc., 119:8111-8112 (1997).
Poths, H. et al., "From monomeric to polymeric ferroelectric liquid crystals. A comparative study of ferroelectric properties", Liq. Cryst. 18:811-818 (1995).
Ross, D.L. "Photochromic indigoids. III: A photochromic element based on the cis-trans photoisomerization of a thioindigo dye", Appl. Optics 10:571-576 (1971).
Wakemoto, H. et al. "Optically active thioindigo dyes for liquid crystals", Abstract, Chem. Abstr. 108:7503y (1988).
Wakemoto, H. et al. "Liquid crystal composition containing thioindigo dyes", Abstract, Chem. Abstr. 108:46959w (1988).
Walba, D.M. et al., "Design and synthesis of new ferroelectric liquid crystals. 14. An approach to the stereocontrolled synthesis of polar organic thin films for nonlinear optical applications", J. Am. Chem. Soc., 113:5471-5474 (1991).
Walba, D.M. et al., "Main-chain ferroelectric liquid crystal oligomers by acyclic diene metathesis polymerization", J. Am. Chem. Soc. 118:2740-2741 (1996).
Walba, D.M. et al., "An approach to the design of ferroelectric liquid crystals with large second order electronic nonlinear optical susceptibility", Mol. Cryst. Liq. Cryst., 198:51-60 (1991).
Walba, D.M. et al., "Ferroelectric liquid crystals for nonlinear optics: orientation of the disperse red 1 chromophore along the ferroelectric liquid crystal polar axis", J. Am. Chem. Soc., 118:1211-1212 (1996).
Whitten, D.G., "Photochemical reactions in organized monolayer assemblies. I. Cis-trans isomerization of thioindigo dyes", J. Am. Chem. Soc. 96:594-596 (1974).
WPIDS 87-245995, 1987.
WPIDS 87-245972, 1987.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Compounds and methods for doping liquid crystal hosts does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Compounds and methods for doping liquid crystal hosts, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Compounds and methods for doping liquid crystal hosts will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1217380

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.