Compound useful for the preparation of a 1-olefin polymer

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 11, 556 12, 556 13, 556 19, 556 20, 556 21, 556 42, 556 43, 556 52, 556 53, 502155, 526127, 526160, 526943, C07F 710

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active

056798121

ABSTRACT:
A very efficient catalyst system for the polymerization of 1-olefins consists of an aluminoxane and a metallocene which is a compound of the formula I ##STR1## in which R.sup.1 and R.sup.2 denote hydrogen atoms, halogen atoms or hydrocarbon radicals and R.sup.3 and R.sup.4 are mononuclear or polynuclear hydrocarbon radicals which can form a sandwich structure with the central atom and which are linked to one another by a --R.sup.6.sub.m --R.sup.5 --R.sup.7.sub.n -- bridge containing a hetero atom and consisting of one or several members.
The catalyst system produces polymers having a high molecular weight and excellent grain morphology.

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Ewen et al, "Crystal Structures and Stereospecific Propylene Polymerization with Chiral Hafnium Metallocene Catalysts", J. Am. Chem. Soc. 109, pp. 16544-6545 (1987).
Kaminsky et al., "Transition Metals and Organometallics as Catalysts for Olefin Polymerization", Proceedings of an International Symposium, Hamburg, Sep. 21, 1987-Sep. 24, 1987, pp. 281-289 (1988).
Kaminsky et al., "Olefinpolymerization with Highly Active Soluble Zirconium Compounds Using Aluminoxane as Cocatalyst", Makromol, Chem., Macromol. Symp. 3, pp. 377-387 (1986).
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