Compositions for high power piezoelectric ceramics

Compositions – Piezoelectric – Lead – zirconium – titanium or compound thereof containing

Reexamination Certificate

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C310S311000

Reexamination Certificate

active

07547401

ABSTRACT:
Piezoelectric compositions of the formula Pb(1-z)Mz(Mg1/3Nb2/3)x(ZryTi1-y)1-xO3where M can be either Sr or Ba or both, x is between about 0.35 and about 0.40, y is between about 0.36 and about 0.42, and z is between about 0.04 and about 0.08. The piezoelectric ceramic is provided as a composite perovskite structure. Additional materials or dopants can be added to the piezoelectric ceramic of the present invention. Example of dopants that can be added to the piezoelectric ceramic include, but are not limited to: MnO2, Ni2O3, TeO3, TeO2, MoO3, Nb2O5, Ta2O5, CoCO3, and Y2O3. The piezoelectric ceramics of the present invention can be used to fabricate piezoelectric elements for a wide variety of devices that can be fabricated to exhibit high power applications including miniaturized displacement elements, buzzers, transducers, ultrasonic sensors and ultrasonic generators, and the like.

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Abstract for DE 1,646,699.
Structural compositional and piezoelectric properties of the sol-gel Pb(Zr0.56Ti0.44)0.80(Mg1/3Nb2/3)0.20O3/Pb(Zr0.56Ti0.44)O3composite films; K. Sumi, H. Qiu, H. Kamei, S. Moriya, M. Murai, M. Shimada, T. Nishiwaki, K. Takei, M. Hashimoto; Thin Solid Films, pp. 270-275; Elsevier Science S.A.; Jan. 21, 1999.
Effects of uniaxial stress on dielectric properties lead magnesium niobate-lead zirconate titanate ceramics; R. Yimnirum, S. Ananta, E. Meechoowas, S. Wongsaenmai: Dept. of Physics, Chiang Mai Univ., Chiang Mai, Thailand; IoP electronic journals, Journal of Physics D: Applied Physics pp. 1615-1619; Jun. 18, 2003.
Mechanical Properties ofxPMN-(1-x)PZT Ceramic Systems; R. Yimnirum, E. Meechoowas, S. Ananta and T. Tunkasiri; Dept. of Physics, Chiang Mai Univ., Chiang Mai Thailand/ CMU Journal (2004) vol. 3(2); pp. 147-154.
Structure and the location of the morphotropic phase boundary region in (1-x)[Pb(Mg1/3Nb2/3)O3]-xPbTiO3; A. Singh and D. Pandey; School of Materials and Technology, Institute of technology, Banaras Hindu Univ., Varanasi, India; IoP electronic journals; Journal of Physics: Condensed Matter pp. 931-936; Nov. 16, 2001.
Morphotropic phase boundary in Pb(Ni1/3Nb2/3)O3-PbTiO3solid solution system; K. Chen, C. Lei, X Zhang, J. Wang; Materials Science and Engineering B99 (2003) pp. 487-490; Elsevier Science B.V.; Sep. 15, 2002.
Morphotropic phase transition studies in Pb(ZrxTix)O3by far-infrared reflectance spectroscopy (abstract); V. Sivasubramanian, V R K Murthy, B. Viswanathan, M. Sieskind; Dept. of Physics, Indian Institute of Technology, Madras—600 036, India; IoP electronic journals; Journal of Physics: Condensed Matter; Apr. 1, 1996.

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