Composition useful in process for preparing powadir membranes fr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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521 64, 521 85, 521 87, 521 88, 521 89, 521 90, 521 94, 521 97, 521 95, 521 98, 521180, 524611, C08L 6900

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049621319

ABSTRACT:
The invention is a composition useful for the preparation of POWADIR membranes of a bisphenol-based polycarbonate wherein at least 25 percent by weight of the bisphenol moieties are tetrahalogenated, wherein the halogen is Cl or Br, the composition comprising (i) a bisphenol-based polycarbonate wherein at least 25 percent by weight of the bisphenol moieties are tetrahalogenated, wherein the halogen is Cl or Br, (ii) a solvent for such polycarbonate, and (iii) a non-solvent for such polycarbonate. The composition is useful for extruding membranes wherein the membranes formed are POWADIR membranes with a discriminating region capable of separating oxygen from nitrogen.
The composition of this invention allows the formation of membranes with excellent physical properties, good separation factors for oxygen and nitrogen, with excellent fluxes.

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Muruganandam, University of Texas at Austin, Paper entitled "Absorption and Transport in Substituted Polycarbonates and Polystyrene/Tetramethyl Polycarbonate Blends", 10/28-29/85.
Chern et al., Chapter 2, "Material Selection for Membrane Based Gas Separations", Material Science of Synthetic Membranes, Lloyd, Ed., pp. 25-46, American Chemical Society (1985).

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