Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...
Reexamination Certificate
2001-08-16
2003-09-16
Nutter, Nathan M. (Department: 1711)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Mixing of two or more solid polymers; mixing of solid...
C524S427000, C524S436000, C524S451000, C524S515000
Reexamination Certificate
active
06620891
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a polypropylene resin composition comprising an ethylene-propylene copolymer having low molecular weight and an ethylene-propylene copolymer having high molecular weight but both have different constant melt flow rates. This polypropylene resin composition exhibits excellent physical properties such as impact resistance, heat resistance (thermal deformation resistance) and scratch resistance and thus, it can be substitutable for conventional ABS/PC resins and improve reclamation of automotive plastic parts such as housing assembly glove box parts due to deletion of coating process.
BACKGROUND OF THE INVENTION
In general polypropylene resin is widely used in automotive interior parts due to its low cost. This polypropylene resin is about ⅓ price of ABS/PC resins. However, uses of polypropylene resin have been limited to low grade parts of automobiles because of inferior impact resistance, heat resistance and scratch resistance so that, with aims of overcoming such problems, various polypropylene resins which provide improved physical properties have been intensively proposed.
However, conventional polypropylene resins have poor impact resistance, resulting in cracks in the products during real vehicle crash test relating to the requirement tests in North America and Europe, low heat resistance and poor scratch resistance and further require additional coating process of primer compared to ABS/PC resins.
Therefore, polypropylene resins cannot be used for high functionalities of automotive interior parts such as housing assembly glove box even if the price of the conventional resins is ⅓ of ABS/PC.
SUMMARY OF THE INVENTION
The present invention has been completed to add ethylene-propylene copolymers having different molecular weights into the conventional polypropylene polymer composition to be free from the above-mentioned problems created by poor impact resistance, heat resistance and scratch resistance of the conventional polypropylene resins.
An object of the present invention is to provide polypropylene resin composition which can be substituted for 3 times high price of ABS/PC resins by satisfying physical properties required for the parts of automobile housing assembly glove box and deleting coating process which was required for the conventional resins, so that cost and weight can be lowered, and improve reclamation process of plastic parts.
DETAILED DESCRIPTION OF THE INVENTION
The present invention is characterized by polypropylene resin composition comprising:
(i) 20-60 wt. % of ethylene-propylene compolymer having low molecular weight, an ethylene content of from 5 to 20 wt. % and melt flow rate of from 5 to 40 g/10 min;
(ii) 20-60 wt. % of ethylene-propylene compolymer having high molecular weight, an ethylene content of from 5 to 20 wt. % and melt flow rate of from 0.3 to 5 g/10 min; and
(iii) 5-40 wt. % of an inorganic filler having a particle size of from 1 to 10 &mgr;m.
The present invention is described in more detail as set forth hereunder.
The present invention is characterized by having two-types of ethylene-proplyene compolymers having different molecular weights in the polypropylene resin composition.
It is preferred to use 20-60 wt. % of ethylene-propylene compolymer having low molecular weight and an ethylene content of from 5 to 20 wt. %. Especially, the ethylene-propylene compolymer of the invention has a melt flow rate of from 5 to 40 g/10 min, weight average molecular weight of from 200,000 to 400,000, number average molecular weight of from 50,000 to 80,000 and a specific gravity of from 0.89 to 0.91.
The other ethylene-propylene compolymer having high molecular weight and an ethylene content of from 5 to 20 wt. % is preferably used in the range of from 20 to 60 wt. %. When ethylene-propylene copolymer having high molecular weight is less then 20 wt. %, impact strength is degraded. On the other hand, it is not desired for ethylene-propylene copolymer to exceed 60 wt. %, because when it is more than 60 wt. %, processability is degraded.
The ethylene-propylene compolymer of the invention has a melt flow rate of from 0.3 to 5 g/10 min, weight average molecular weight of from 400,000 to 500,000 and number average molecular weight of from 800,000 to 100,000.
Typical inorganic filler is added to two ethylene-propylene complymers having different molecular weights and examples thereof are talc, barium sulfate and potassium carbonate. It is preferred to use the filler having an average particle size of from 1 to 10 &mgr;m and when the particle size is larger than 10 &mgr;m, distribution of resin may be degraded and thus, it does not provide the desired physical properties.
Said inorganic filler is used in the range of from 5 to 40 wt. % to the entire polypropylene resin composition. When it is less than 5 wt. %, physical properties such as mechanical strength and rigidity and scratch resistance are inferior. On the other hand, when it is more than 40 wt. %, processability and impact resistance are inferior.
Other additives, used by one having ordinary skill in the art, such as an anti-oxidant, a neutralizer, an anti-static agent, and a nucleating agent may be arbitrarily incorporated in an appropriate content not to obstruct the above-mentioned object of the present invention. Examples of anti-oxidant are phenols, phosphates, and thiodipropionate syilergists and examples of neutralizer are calcium stearate and zinc oxide.
The polypropylene resin composition of the present invention is prepared by means of commonly-known method and it is described briefly hereunder.
Each component is mixed and filled in the hopper of the extrude. After it is supplied with constant ratio into barrels at an appropriate temperature and mixed, it is passed to a condenser, cut and molded with injection molding machine to obtain the desired product. The obtained product is preferred to have a melt flow rate of from 3 to 40 g/10 min. When it is lower than 3 g/10 min, processability may be degraded and flow mark of the product may occur. On the other hand, when it is higher than 40 g/10 min, physical properties such as strength, rigidity, and impact strength become poor.
The final product is prepared by adding other essential additives to the polypropylene resin composition to give master batch powder which is further blended to give pellets. The pellets can be used to manufacture automotive interior parts.
Hereunder is given a more detailed description of the present invention using examples. However, it should not be construed as limiting the scope of this invention.
REFERENCES:
patent: 4758627 (1988-07-01), Wilkus et al.
patent: 6251997 (2001-06-01), Imai et al.
Im Young-Ho
Yu Young-Hwan
Christie Parker & Hale LLP
Hyundai Motor Company
Nutter Nathan M.
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