Composition of antioxidants of reduced volatility

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 4595C, C08K 537, C08K 513

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active

040091473

ABSTRACT:
For incorporation in normally oxidizable polymers, polymeric antioxidants characterized by repeating hindered bisphenolic units, the average number of said units per polymeric chain in said composition being from about 2 to 10, preferably about 2 to 7, most preferably about 2 to 4. The antioxidants are prepared by oxidative coupling of appropriate bisphenols, as by reaction with a ferricyanide coupling agent. Polymer-antioxidant combinations formed according to the invention have excellent high temperature oxidative stability, high resistance to polymer damage by massive doses of ionizing radiation and the antioxidant does not release significant amounts of condensable species when subjected simultaneously to conditions of high vacuum and elevated temperatures.

REFERENCES:
patent: 2239534 (1941-04-01), Mikesa
patent: 2905737 (1959-09-01), Webb
patent: 2956982 (1960-10-01), McCall et al.
patent: 3082187 (1963-03-01), Fuchsman
patent: 3450671 (1969-06-01), Thalstrup
patent: 3843600 (1974-10-01), Robin
patent: 3856728 (1974-12-01), Akramoff
Wire and Wire Products-36 (4) p. 465 (1961) article by Tarbox.

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